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Direct Dyes. These watersoluble anionic dyes, when dyed from aqueous solution in the presence of electrolytes, are substantive to, i.e., have high affinity for, cellulosic fibers. Their principal use is the dyeing of cotton and regenerated cellulose, paper, leather, and, to a lesser extent, nylon. Most of the dyes in this class are polyazo  compounds,  along  with  some stilbenes, phthalocyanines,  and  oxazines. Aftertreatments, frequently applied to the dyed material to improve washfastness properties, include chelation with salts of metals (usually copper or chromium), and treatment with formaldehyde or a cationic dyes complexing resin.
 Vat Dyes. These waterinsoluble dyes are applied mainly to cellulosic fibers as soluble leuco salts after reduction in an alkaline bath, usually with sodium hydro- gensulfite. Following exhaustion onto the fiber, the leuco forms are reoxidized to the insoluble keto forms and aftertreated, usually by soaping, to redevelop the crystal  structure.  The  principal  chemical classes  of vat  dyes  are  anthraquinone and indigoid. 
 Cationic (Basic)Dyes. These  watersoluble cationic  dyes are  applied  to paper, polyacrylonitrile (e.g. Dralon), modified nylons, and modified polyesters. Their original use was for silk, wool, and tanninmordanted cotton when brightness of shade  was  more  important than fastness  to  light  and  washing.  Basic dyes  are watersoluble and yield colored cations in solution. For this reason they are frequently referred to as cationic dyes. The principal chemical classes are diazahemicyanine,  triarylmethane,  cyanine,  hemicyanine,  thiazine, oxazine,and  acridine. Some basic dyes show biological activity and are used in medicine as antiseptics.
 Acid Dyes. These watersoluble anionic dyes are applied to nylon, wool, silk, and modified acrylics. They are also used to some extent for paper, leather, ink-jet printing, food, and cosmetics.
Solvent Dyes. These water-insoluble but solvent-soluble dyes are devoid of polar solubilizing groups such as sulfonic acid, carboxylic acid, or quaternary ammonium. They are used for coloring plastics, gasoline, oils, and waxes. The dyes are predominantly  azo  and anthraquinone, but  phthalocyanine  and  triarylmethane dyes are also used.

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